Time control for generation and ractions of trichlorovinyllithium species

publication
publication

Flash Chemistry Using Trichlorovinyllithium. Switching the Reaction Pathways by High-Resolution Reaction Time Control.
Nagaki, A.; Takahashi, Y.; Henseler, A.; Matsuo, C.; Yoshida, J.
Chem. Lett. 2015, 44, 214–216.
DOI: 10.1246/cl.140980

Generation and reaction of the unstable intermediate trichlorovinyllithium species. By controlling the reaction time, the intermediate structure is altered, enabling the switching of the product.