Generation of Hazardous Methyl Azide and Its Application to Synthesis of a Key-Intermediate of Picarbutrazox, a New Potent Pesticide in Flow
Ichinari, D.; Nagaki, A.; Yoshida, J.
Bio. Med. Chem. 2017, 25, 6224–6228.
DOI: 10.1016/j.bmc.2017.07.005
The explosive methyl azide was generated in a flow microreactor and promptly utilized for synthesis, demonstrating the synthesis of a precursor to the fungicide picarbutrazox.
